Ali Mirza1, James
R. Woodyard1 and David B. Snyder2
1 Wayne State University,
Department of Electrical & Computer Engineering, Detroit, MI 48202
2NASA Glenn Research Center,
Cleveland, OH 44135
Air
mass zero calibration of solar cells has been carried out for several years by
NASA Glenn Research Center using a Lear-25 aircraft and Langley plots. The calibration flights are carried out
during early fall and late winter when the tropopause is at the lowest
altitude. Measurements are made
starting at about 50,000 feet and continue down to the tropopause. A joint NASA/Wayne State University program
called Suntracker is underway to explore the use of weather balloon and communication
technologies to characterize solar cells at elevations up to about 120
kft. The balloon flights are low-cost
and can be carried out any time of the year.
Results of cell characterization with the Suntracker are reported and
compared with the NASA Glenn Research Center aircraft method.
We have carried out an extensive review of mountaintop,
aircraft and balloon methods for characterizing solar cells and producing
laboratory standards [1]. Our focus in
this paper is to compare measurements using aircraft and balloon methods.
The evolution of solar-cell technology for space
applications has resulted in “state-of-the-art” cells with four and five
junctions in series. Each junction is designed
with a spectral response matched to one region of the spectral irradiance of
AM0 in order to optimize the efficiency of solar cells. The current in a
four-junction solar cell operating at a given voltage is:
(1)
where
is the absolute AM0 spectral irradiance of sunlight and
is the spectral
response of the cell at wavelength
and voltage
. In the ideal case,
the spectral response is independent of the irradiance of the light source.
The evolution of solar-cell technology for space
applications has resulted in “state-of-the-art” cells with four and five
junctions in series. Each junction is
designed with a spectral response matched to one region of the spectral irradiance
of AM0 in order to optimize the efficiency of solar cells. The current in a
four-junction solar cell operating at a voltage that is given by:
(2)
and
(3)
where
the variables in Equation 2 are the same as in Equation 1 except
and
are the lower and upper cut-off wavelength values, above and
below which the spectral response is negligible and no longer contributes to
cell current. The spectral response in
Equation 2 characterizes the overall operation of the four junctions in optical
absorption and carrier transport.
However, the spectral responses and voltages in Equation 3,
and
respectively, are
subscripted to show that they are different for each of the four
junctions. The voltage across the cell
is equal to the sum of the voltages across each of the four junctions, namely,
. The wavelength
ranges on each of the integrals, in the most general case, will overlap since
it is not possible to fabricate materials with sharp wavelength cut-offs. Equation 3 shows the series nature of the
current in multi-junction solar cells, namely, the current is the same in each
of the junctions.
Current reduction due to a change in spectral irradiance
in one region of the spectrum must be accomplished through changes in spectral
responses of the other three junctions; this is the case because the spectral
irradiances in the other three wavelength ranges are assumed to be the same as
AM0. The collective interaction of the
four junctions will result in redistribution of the cell voltage across the
four junctions, which in turn changes the spectral responses of the four
junctions and the cell current. It is
clear that the voltage dependence of the spectral responses of multi-junction
solar cells complicates optimization of cell design. While there are characterization methods that make it possible to
use solar simulators in advancing the multi-junction solar cell technology, the
series nature of the cells places more demands on the need for standard cells
characterized under AM0 conditions. AM0
conditions are available only in space; near AM0 conditions can be achieved at
altitudes in excess of 100,000 ft. The
demand for greater access to AM0, and the costs associated with AM0
calibration, has generated interest in exploring low-cost methods for AM0 solar
cell calibration. The NASA supported
Suntracker program is an attempt to meet this challenge.
AIRCRAFT METHOD
The
aircraft method has been developed over the years by investigators at NASA
Glenn Research Center [2-6]. A large
body of calibration data has been collected and AM0 standards provided to the
PV community. The aircraft has been
replaced twice and the method improved.
The current aircraft is a Lear 25 that houses the instrumentation and
collimator in a pressurized and temperature controlled compartment. Photographs of the Lear 25 aircraft, collimation
tube and test cell may be viewed on the NASA Glenn Research Center Web site
[7]. Measurements are carried out every
nine seconds during a 6E-4 air mass per second rate of descent from 50 kft down
to the tropopause. Sources of random
error are estimated to be about 0.04 % and agree with measurements. The difference in the average of
measurements on a single-junction cell carried out over a twenty-year period
and a recent measurement was at the 0.05 % level. Systematic errors were estimated to be at the one percent
level. Space shuttle AM0 short-circuit
current measurements on two cells were compared with the aircraft method. The aircraft measurements were less than the
shuttle measurements by 1.0 and 0.8 % for the two cells; the errors were
consistent with the estimated systematic errors.
Recent
investigations of the role of ozone on the solar cell AM0 short-circuit current
that have improved the aircraft method have been investigated by Snyder and collaborators
[8,9]. The ozone correction method called for first correcting the
short-circuit current measured at each altitude for ozone absorption, then
plotting the data and extrapolating to air mass zero. The approach requires the column ozone at
each of the altitudes at which the cell current is measured. The TOMS standard ozone profiles were used
to calculate column ozone as function of altitude [10]. Figure 1 shows the TOM ozone profiles used
in calculating the column ozone. The
ozone density shown in the figure at 156,000 ft includes the ozone above
156,000 ft. The profiles in the figure
are for mid latitudes and total column ozone values ranging from 175 to 475
d.u., denoted by 175M-475M in the figure.
Mid latitudes are around 45 degrees north, the latitude of the NASA
Glenn Research Center flights. The
maximum altitude for the flights is about 50,000 ft. Figure 1 shows the fraction of the total column ozone above
55,000 ft decreases with increasing total column ozone. The fraction at 55,000 ft is about 0.87 of
the total column ozone when the total column ozone is 175 d.u.; the fraction
decreases to about 0.77 at 475 d.u. The
fraction is about 0.92 and fairly independent of total column ozone at 40 kft.
The ozone AM0
short-circuit current correction method included converting the aircraft
altitudes to atmospheric pressure,
. The total column
ozone on the day of the flight was obtained and used to select the appropriate
TOMS ozone profile in Figure 1. The
fraction of the total ozone column
above the aircraft during each of the measurements was
calculated. The ozone corrected
short-circuit current
was calculated for
each measurement
using:
(4)
The ozone corrected
short-circuit currents were plotted as a function of pressure on a Langley
plot, instead of a function of air mass.
The linear plot was extrapolated to zero pressure to determine the AM0
short-circuit current. Data collected
over two time intervals, namely a short term and long term, were compared. The short-term data were collected on one
cell during twenty flights in one year.
The long-term data were collected on the same cell during thirteen flights
over a period of eight years. The
percent standard deviations are reduced for both the cells as was observed for
the Si cell, again confirming the importance of the ozone correction. The differences in the high and low current
values are reduced for both cells when the revised method is used. A larger zenith angle results in a larger
correction in the AM0 short-circuit currents for both cells. The revised method is more effective in
correcting for larger zenith angles as is illustrated by the smaller high-low
percentage differences in the AM0 short-circuit currents. However, there is a trend for corrected
currents to exhibit a decreasing trend with increasing zenith angle.
BALLOON METHOD
A joint NASA Glenn Research Center/Wayne State University
program called Suntracker is underway to explore the use of weather balloon and
communication technologies to characterize solar cells at elevations up to
120,000 feet [11-13]. The balloon
flights are low-cost and can be carried out any time of the year. Details on the program and photographs are
available on a Web site [14].

Seven flights have been
attempted with five successful launches.
The scientific package was retrieved on the same day for the Suntracker
I, III and IV flights. Hardware problems
developed during the Suntracker VI and VII flights that resulted in the loss of
GPS signals; the package was found within a few days of the launch by individuals
and subsequently retrieved. A
single-junction silicon solar cell was mounted in the collimator during the
flights. The cell voltage data down
linked during the Suntracker IV and VI flights have been analyzed using Langley
plots to determine the AM0 short-circuit current. The Suntracker IV uncorrected short-circuit current versus
altitude is shown in Figure 2. Only the
maximum currents were selected for use in the Langley plot. The cell current data illustrate the
tracking characteristics during the ascent.
For the most part the Suntracker was not locked on the sun during the
flight. The video data showed the motors
slowed down during the ascent as a result of the low atmospheric
temperatures. Motor assemblies using
lubricant with lower temperature specifications will be evaluated in future
flights. Additionally, the stability of
the scientific package and the collimator control algorithm will be
investigated in order to improve the performance of the Suntracker system.
Figure
3 is a Langley plot of the data for a single-junction silicon solar cell from
the Suntracker IV and VI flights. The
data have been corrected for the earth-sun distance, ozone and cell
temperature, and fit with straight lines.
The extrapolated AM0 short-circuit currents are 144.32 and 144.38 mA for
the Suntracker IV and VI measurements, respectively. The average AM0 short-circuit current is 144.35 mA
0.02 %. The
resolution of the eight-bit ADC in the Suntracker data acquisition system is
0.2 %, showing that the agreement between the two flights is
better than the uncertainty in the measurements and probably reflects the statistics
of the curve fitting etc. The AM0
short-circuit current of the single-junction silicon solar cell flown on the Suntracker flights was determined using
the aircraft method at NASA Glenn Research Center. The AM0 short-circuit current was 144.88 mA and within
0.36 % of the Suntracker average value. The results agree to within the statistics
of the two methods, namely about
0.2 % for the Suntracker measurements and
0.6 % for the aircraft method.
The cell temperature
versus altitude during the Suntracker VI flight is shown in Figure 4. Also shown are the radiosonde data reported
by the National Weather Service (NWS) on the day of the flight. The effect of solar heating on the cell
current is apparent. While the solar
cell temperature increased from –10 to about
0 oC as the balloon ascended from 80,000 to 96,000 ft, the
atmospheric temperature remained at about
–45 oC. The dependence of the cell and NWS temperatures in this altitude range suggests
that the cell temperature may be higher at higher altitudes. If this is the case, it will be possible to
operate cells closer to 25 oC at higher altitudes, and to determine the
temperature coefficient of the short-circuit current as the package ascends.
It
is instructive to determine the atmospheric optical absorption coefficients for
the two Langley plots. The slopes of
the two straight lines in Figure 3 were analyzed to determine the absorption
coefficients; the coefficients are 0.265 and 0.293 per air mass for the
Suntracker IV and VI data, respectively.
The average value of the atmospheric optical absorption coefficient is 0.280 per air mass
5 %. An analysis of
the Langley plot produced with aircraft data gives absorption coefficients of
0.125 per air mass. The Suntracker
value is somewhat larger than the 0.20 per air mass determined from the earlier
aircraft measurements [2] while the absorption coefficients determined with the
current aircraft data is considerably less.
The reasons for these differences are not understood and will be the
subject of future investigations.
CONCLUSIONS
The voltage dependence of
the spectral responses of multi-junction solar cells complicates optimization
of cell design. The series nature of
multi-junction solar cells places more demands on the need for standard cells
characterized under AM0 conditions. The AM0
short-circuit current of a single-junction silicon solar cell was determined
using data collected during two Suntracker flights. The agreement in the two measurements was
0.02 %. The agreement
in the AM0 short-circuit current of the cell measured with the Suntracker balloon
method and NASA Glenn Research Center aircraft method was
0.36 %, which is within the uncertainty of the two methods. There is a need to understand the role of
ozone and atmospheric optical absorption on the calibration of solar cells in
the stratosphere.
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